I've been looking into this myself, being a vintage steel fan. It's an interesting subject, to me at least. From what I've been able to deduce, for a LARGE sized butted steel road frame & forks, say 23", the very lightest ones will tip the scales at about 5lbs (typically Reynolds 753), and the heavy end of the scale 531ST/501 DB will be close to 6lbs. That is just the frame & forks, not including the BB and headset.
Presumably, quality non-butted steel such as Reynolds 500 cro-moly and 531plain gauge will be a little over 6lbs, assuming the same lugs, dropouts, BB shell etc.