Next time you see a fuel truck replenishing at a branded garage, why not wait for the driver to finish and ask him. The same RON gets into supermarket station from the same tanker during the run and they come from the same refinery. Ask politely and he may even show you the delivery logs.
@Baldy is right
Supermarket don't sell inferior fuel if it i the same RON. Higher the RON, the engine gets better treatment and hence better price.
Slight variations on the higher RON where brands do fuel additives blending for marketing and brand differentiations are more targeted at cleaner engines. Mileage will be within the same zone RON for RON.
Refiners rarely touch the refining process output as prices are volatile and supply comes from all over the World. Refiners biggest issue is sulphur content and to bring it within specs as untreated oil from different fields differs widely
Supermarket fuel is also part of the loss leader bucket such as eggs and milk. Its to draw customers and whack you hard on branded detergents, toothpaste, washing powder and organic and free range products.
If fuel of the same RON differs in performance there would have been comparisons tables run by some brands and consumer organisations.