ColinJ said:You beat me to it! I had what I thought was an impossibly seized pedal once and went along to the LBS with my bike. They reached for the pedal spanner and I was about to tell them not to bother when they fished out what was virtually a length of scaffold pipe about 4 feet long. One guy held the bike and another stood on the end of the pipe. There was a loud Crack! which sounded like the crank breaking, but it was just the pedal coming loose .
Or, If you have a good strong spanner which is a good fit, secure the crank, preferably in a vice and hit the spanner a good crack with a decent sized hammer (hit it, don't tap it gently which would be a waste of time). The shock will usually be enough to free it. But if you are doing this or putting a pipe over the spanner, it needs to be a a good fit and the crank needs to be well secured. I can't see how it should be that tight anyway and it shouldn't corrode too much.