tiny spacer in the freehub central axel locking nut moved the whole free hub and cassette a couple of mm away from the dropout and the point of fix for the whole rear axel is now centred on the central axel
"Gunked up spacer" within the cassette? Incompatible with description above. The OP says that they inserted a 2mm washer inside the freehub locknut (on the axle) thus moving the locknut 2mm 'out' and proud of the cassette lockring.
Note this didn't move the cassette relative to the wheel, but did effectively move it 2mm left cf right dropout.
This implies that the whole wheel will now be one mm left of centre, relative to the frame.
Have you had to adjust rim brakes? (Ignore Q if discs, because the rotor will still be perfectly aligned, on the right side: that locknut hasn't moved.)
Question to the OP: Taking the QR out, is the protruding axle the same length both sides now (and for a bonus, how many mm)?