If you're comparing new with old, then a newer design frame is likely to perform better and be more comfortable to ride while it's doing it than an older frame, regardless of the material used in its construction. (Of course, there will be exceptions to this, but I haven't come across any personally.)
If you're simply comparing new bikes in different materials, the differences in performance and comfort are much smaller, although alu generally gives a relatively harsh ride (which is why alu bikes often have carbon forks). I think choice of frame material is mostly down to personal preference, and you just need to ride bikes made from different materials to find out which you like best.