What type of post is it if its alu spray something like wd-40 on leave overnight and try again. If its Carbon DONT. Sometimes I find rotating the post, gradually at first before pulling up helps.
Try GT85 / WD40. Put the seatpost in a vice and try twisting the frame.
If this doesn't work have a look under the sink for something containing ammonia. Ammonia should disolve aluminium oxide.
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