Andy in Sig said:
In diamonds the carbon is most definitely locked into one structure but I can't think of a reason why the various isotopes couldn't form parts of that structure. At this point we need a chemist.
Ooh, got you thinking now!
Living things incorporate carbon into their bodies as they grow - virtually everything in your body is made on a carbon skeleton. Anyhow, living organisms incorporate C in its isotopes C12 and C13 (which are stable) and a teeny bit of unstable C14. These exist in a precise ratio in nature and so, in a living organism, C will be present in this ratio.
When an organism dies, it stops incorporating carbon. Scientists can measure the amount of C14 in a sample and determine its proportion. C14 has a half life of about 5500 years, and so, it is possible to determine when the specimen stopped assimilating carbon - ie died.
Diamonds are made of pure carbon. Again in the natural ratio of C12 to C13 to C14. However, the crystal diamonds were physically formed millions and millions of years ago. Over this geological period of time, the C14 will more or less all have decayed (it has a half life of about 5500 years) so there will be pretty much none left with which to date the sample.
Carbon dating is only really any use when used to date items up to a few tens of thousands of years old.