Just in case anybody ever encounters this problem ... new cassette came today and lo and behold no slipping. I compared the new 15 tooth sprocket with the old one and as far as I could see it looked identical apart from some very slight wear.You were correct Chris, the sharks tooth shaped cutaway wasnt a chip so the LBS got it wrong which is why filing it off made no difference. It was clearly damaged in some way but I really cant see where especially as the chain was engaged with 12 or so teeth at all times ? The moral being when every other possibily has been dismissed. what's left must be the problem. Thanks to all for the advice , now if it ever stops raining I can go for a ride........