No reason not to - it depends on what you polish it with. If you are using something like Autosol that leaves a clean, polished surface, that's excellent for braking - think how polished a car's discs are. But if you use something else ...
Once in a blue moon I do a deep clean of my bike, as opposed to a quick once over. I use Isopropyl Alcohol for rims and it makes them look spiffing. And then I go for a ride and cover them in crud again.
I once oversprayed some WD-40 onto a motorcycle brake disc by accident. Hardly any brakes at all afterwards. It cleaned off the disc with thinners OK, but ruined the pads. Personally, I wouldn't let WD-40 (or GT-85 or whatever) anywhere near a braking surface. It might evaporate over time, but what are you going to do for brakes until then?
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