KnackeredBike
I do my own stunts
Nickel batteries have totally different chemistry so best to forget about those.But charging a battery after 25% use just seems pointless to me & not what that battery was designed for?
The battery voltage in all batteries including Li-ion changes depending on the charge of the battery - in Li-ion from about 4.2V at 100% to 3.5V when dead. The battery is "happiest" somewhere in the middle, and below 4.05V for all sorts of reasons, mostly internal corrosion and parasitic reactions within the battery.
Now in your smart phone it is more valuable to have as much charge as possible from day one, because the battery and indeed phone are cheap, and indeed battery life is more difficult to quantity because you use it different amounts each day.
Electric cars are much more strict, normally limiting charge to within 80% and 20% to keep voltage in a less "stressful" place for the battery - not least because if you can commute to work, then a year later you no longer have enough charge to, it is more noticeable and much more expensive to fix. I don't know whether eventually there will be an "emergency" 20% to use if you get stuck, or if it would just be abused by people using it every day.