It happened to me yesterday, but with the rear mech. I was churning up a steep hill, dropped two gears to my lowest, and ended up pedalling fresh air. It's a good thing the MTB has a sloping top tube or I would be applying to join the Vienna Boys' Choir. The chain had overshifted and was jammed between the biggest sprocket and the spokes. I have the lower limit screw set pretty carefully, but obviously it needs a tweak. Half a turn backwards with the pedals had the chain in place again, and off I went.