"Have the chain on your largest chainwheel, with the quick-link to the front of it. Hold the crank and pull the lower length of chain forward one tooth on the chainwheel. Move the one tooth’s-worth of slack up and around the teeth, so that the quick-link and one other link form a sticking-out V. Tap the point of the V sharply with a something hard and heavy (a hammer is ideal but a rock will do) and the quick-link will slide open – just like that!’
I tried this method on several chains. Some quicklinks needed little pinch first (or a sharper tap) and it helps to aim at the side of the link without a slot at that end, but if you do that it always works a treat! Ian assures us that there is no danger of damage to the teeth, because the chain is forced into their roots where they are strongest."
http://www.cyclinguk.org/file/member/201107050_0.pdf