betty swollocks
large member
Boon, when in the large ring, as you move to the larger cogs at the rear, at the point the chain stars making that noise, try clicking the shifter as if shifting to the small ring, but only push it until it clicks once rather than all the way, it should move the mech a bit without shifting to the small ring, this is known as trim, and it's very purpose is to avoid noise!
I don't disagree with the principle, but IMO you should be able to use more than half of the cassette in each chainring. I use 7 out of 9 possible ratio's in each the big and small rings and I believe this to be perfectly acceptable practice. In fact I often even use the 8th largest cog when in the big ring when pulling away and I then shift up a couple.
Of course you can do it if your derailleur(s) allow, but, the straighter you keep your chain, the longer it will last and the more efficient will be your pedalling.