Thanks everyone.
Gave this an attempt yesterday.
Removing the bottom bracket was a bit of a mare. It was tight beyond anything I've ever come across before (aside from a locked circular saw screw once!).
Utterly struggling to turn it, I kept doubting I was turning it incorrectly (but nope, according to general wisdom and the linked provided on this thread, I was at least struggling in the right direction). The trouble is the shallow depth of the grooves on the BB cup (?). Hernia inducing.
Contemplated picking up a ratchet set (I should really own a set anyway). In the end I attached my largest wrench to the BB removal tool and gave the end of the wrench a series of 'thwacks' with a hammer. This, thankfully, made the cup give way and I was able to remove both sides.
The new BB cartridge (the UN26) had a plastic cup which I was a little concerned about (should I have been?) but once fitted and tightened it all seemed well.
Crank/pedals back on and it now works a treat. The missus certainly noted the smoother ride (it was 'clunking' pre fix in all fairness).
On the other Carerra, the chain removal/refit was pretty straight forward too. Didn't really need to shorten the chain, and fitted with the two clips (rather than fitting new pin in). Ran through the gears (bike stationary) and chain seemed fine. I did notice when I flipped the chain onto the big chainring (on the crank...excuse the lack of correct terminology!) the chain became stuck/jammed. Sorted it and didn't manage to replicate it, so perhaps it was the join on the chain that wasn't fully secured...not sure. I'll keep an eye on it - any possible culprits for this happening?
Might have been ideal time to fit a new cassette too? Can't see any particular issues with the current one, but then again I'm not 100% what I should be looking for.
I'll also try and pick up some recommended bike lube this week - I'll ditch the WD40!
I next have to re do my gears (left hand side). The cable needs replacing but I've since noticed part of it has broken off. I'll create a new thread with pictures for that one. Not particularly urgent as I can still use the gears (just not switching the large/small chain ring).
Thanks again for the help folks. Possibly a good start for me to look into bike mechanics a little further!