Sorry M
You do not have to change/adjust the chain.
This is my bike on a compact last year, with short cage rear mech..
http://i123.photobucket.com/albums/o312/Monst_photos/DSC00020.jpg
This is my bike with long cage rear mech and added triple (and blingy white bar tape) for this year. As I said, no need to change the chain!
http://i123.photobucket.com/albums/o312/Monst_photos/100_0542.jpg
No shifting problems, no chain slap, no problems whatsoever with running the chain with either chainset or with a short or long rear mech.
I use a long cage on the triple, my mate does not on his triple combo, but he is more mechanically sensative! To use his short cage with his triple he did take off a couple of links, but changing my bike from a double with short cage to a compact with short cage to triple with long cage, I did not need to touch my chain.
Both versions above are using the same 12/27 cassette.
The front derallier adjustment needs fettling when you swap to a triple as you need to change it for a triple type. Because of the chain angle on (on the naughty small small combo) the compact, this occasionally needed a tweak on the rear mech on first install.
The biggest cassette sprocket one could get away with is a 32 on a road bike, but you need a longer b screw.
This is how you do it.
Buy a single 32 sprocket.
Take the 13 or 12 sprocket (they are loose) from your road cassette. Put it to one side.
Put on the 32 sproket on the bike. Put the rest of the cassette on.
Cassette now goes 32/13 (or 12)
Take one Dura Ace b screw (they are longer) and adjust and away to go.
Of course you could just use a triple (or a 9 speed mtb cassette with a nice light n blingy XT/XTR derrailier, with the adjuster done up to cope with 9 speeds for a 10 speed shifter)