Tightening a seat bolt clamp generates/increases a uniform (tangential) tension in the (circular) clamp so the positioning of the bolt doesn't matter. The tightened clamp exerts uniform centripetal force on the seat tube. The slot is designed to allow tangential movement of the seat tube at the slot which avoids a resisting force. But mainly, it allows the necessary (minimal) reduction in effective diameter of the seat tube: needed for the seat clamp function - to ensure sufficient friction (seat post / seat tube) to stop the post twisting or dropping (under rider's weight).
I can't see that the material the seat post is made of makes a difference, other than affecting the means of ensuring sufficient friction. If the tension is going to be limited (eg 6Nm on the bolt) then the co-efficent of friction (μ) must be increased by using paste (or whatever) - grease on the bolt but not on the post.
Aesthetically and aerodynamically the bolt is best placed at the rear, irrespective of the slot position (which is anyway 'normally' at the back).