Will1985 said:
700 refers to the diameter of the wheel at the outer edge of the rim.
700 is an approximation of the outside diameter of the tyre.
in the case of 622x23 - that'll be nearer to 668mm
however, the rim bead diameter is 622. speak etrto, order etrto, think etrto and type in etrto - you won't be caught out.