This should get you somewhere close:
-Have a look at the brake bosses. You should see three little holes for the V spring to engage into. You should also see the end of the spring in one of them. It is usually in the middle of the three holes. If one of the pair is in the middle and the opposing arm spring is in the top hole, this imbalance will make adjustment very tricky.
-Like Colin said, check the blocks are lined up with the rim and don't touch any part of the tyre.
-Look for the barrel adjuster on the lever and unscrew so that it about half way out/in.
-Use a 5mm Allen key to undo the bolt on the top of the V arm holding the cable.
-Hold the arms in with the blocks on the rims. You do not need to worry about toe in with V brakes. The blocks can contact the rim flat.
-With V arms held in with the blocks against the rim, pull any slack in the cable through and do it up via the 5mm Allen bolt.
-Of course, now the wheel won't turn very well. Screw the barrel adjuster on the lever back in making the cable longer and bringing the blocks away from the rim. If you have judged it right, the blocks will be the correct distance from the rims and you'll have plenty of lever adjustment as the blocks wear.
-now you can adjust the Phillips heads to get the arms moving evenly. They oppose each other so you can try a bit of slacking/tightening on opposite screws.
Here's a quick picture of the back of one off the bike. You can see the spring sticking out. This engages the hole in the brake boss and is what the Phillips screw adgusts: