I usually keep the battery below 50% (because that helps lithium ion batteries age slower)
This makes interesting reading with regard to the benefits of part-charging a Li-ion battery. There's a trade off between available capacity and number of recharge cycles (ie longevity). I note the OP desires high capacity (ie to run as long as possible - more than 14 hours. This implies maximum capacity at outset, though mid ride charging (from a battery bank, from a hub dynamo, or from mains at a stop) is clearly a workaround.
"Most Li-ions charge to 4.20V/cell, and every reduction in peak charge voltage of 0.10V/cell is said to double the cycle life. For example, a lithium-ion cell charged to 4.20V/cell typically delivers 300–500 cycles. If charged to only 4.10V/cell, the life can be prolonged to 600–1,000 cycles; 4.0V/cell should deliver 1,200–2,000 and 3.90V/cell should provide 2,400–4,000 cycles.
"On the negative side, a lower peak charge voltage reduces the capacity the battery stores. As a simple guideline, every 70mV reduction in charge voltage lowers the overall capacity by 10 percent. Applying the peak charge voltage on a subsequent charge will restore the full capacity.
"In terms of longevity, the optimal charge voltage is 3.92V/cell. Battery experts believe that this threshold eliminates all voltage-related stresses; going lower may not gain further benefits but induce other symptoms. (See
BU-808b: What causes Li-ion to die?) Table 4 (see link) summarizes the capacity as a function of charge levels. (All values are estimated; Energy Cells with higher voltage thresholds may deviate.)
"Most chargers for mobile phones, laptops, tablets and digital cameras charge Li-ion to 4.20V/cell. This allows maximum capacity, because the consumer wants nothing less than optimal runtime. Industry, on the other hand, is more concerned about longevity and may choose lower voltage thresholds. Satellites and electric vehicles are such examples."